Let L = −div(A∇) be a uniformly elliptic operator in Rn with real, symmetric, measurable coefficients. We study the identity of two families of Besov spaces Bs,L p,q and Bs p,q , where the former one is defined using the heat semigroup of L, while the
latter one is defined in a classical way, using the metric structure of Rn. A sharp range of parameters p, q, s ensuring the identity Bs,L p,q = Bs p,q is given by a Hardy– Littlewood–Sobolev–Kato diagram.